NASA scientists recently briefed the White House on a discovery made by the Phoenix lander. The blogosphere and editorial pages across the Western world were rife with speculation–had life been discovered? Was there the potential for life? Was there evidence (through spectroscopic analysis) of complex organic molecules?
In the end, it was the discovery of perchlorate that was supposedly so momentous.
Perchlorate is an anion with four oxygen atoms and one chlorine atom. The chlorine atom has an oxidation state of +7 in order to accommodate the the demands of bonding to the oxygen atoms. Despite its high oxidation state, it is actually quite stable due to two things–one is that in that oxidation state with four oxygen atoms, the chlorine is considered to be a “closed shell,” which lends stability to an otherwise potentially unstable species. The other is that the perchlorate is likely stabilized by several “resonance” forms, in which the the electron density of the covalent bonds is distributed more or less equally across the entire molecule.
Perchlorate is typically formed in areas devoid of water that have a high salt content, such as deserts or dry lake beds. It can be formed industrially by reacting chlorine gas with a strong base. Perchlorate can be used in rocket fuel and fireworks, due to its high oxidation potential and its relative stability. My first thought when I heard the the Phoenix lander had found perchlorate was that somehow, the lander had contaminated the sample site. However, NASA claims that the Phoenix lander used a pure hydrazine fuel (two amine groups linked by a single N-N bond), which rules out contamination.
Are the conditions proper for the spontaneous formation of perchlorate? At this point, further laboratory tests are needed to verify that the conditions on the Martian surface are correct. There is evidence that this can happen on Earth, but given the wildly different levels of temperature, pressure, and UV exposure, I would feel more comfortable with results which illustrated the formation of the anions.
A strong oxidizing compound isn’t always good news for species struggling to survive, but there is at least one example that I could find that shows that perchlorate could be used as an energy source for a bacteria-like organism. Again, given the harsh conditions on the surface, I’m not sure how much this could be true.
At this point, no one can say anything for sure, aside from two facts:
- There is water in the regolith on Mars. NASA cannot accurately quantify the amount. At best, all they can do is guess. Anyone that tries to provide a quantity here is acting with insufficient data.
- There is the presence of a compound that could act as an energy source, but this is atypical of life as we know it.
This brings up my last point, in that we are anthropomorphizing our search for life. Who says that life has to operate according to our known parameters? There may be a completely different way of energy acquisition and waste processing that we can’t even fathom because we’ve been so blinded by our evolutionary history and mechanisms of energy production. I’m completely for the search for “life as we know it,” but I feel as though we should be prepared mentally for “life as we don’t know it.” Too often, we’ve been blinded by our own preconceptions that we miss the answers that are right in front of our collective faces. I’d hate to see that happen now.
Pete on August 9th 2008 in Science, Space Advocacy